‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry     

Haosheng Wu  Roman Bttger  Frdric Couffignal  Jens Gutzmer  Joachim Krause  Frans Munnik  Axel D. Renno  Ren Hübner  Michael Wiedenbeck  Ren Ziegenrücker 《Geostandards and Geoanalytical Research》2019,43(4):531-541

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.  相似文献   

Object‐oriented tracking of thematic and spatial behaviors of urban heat islands     

Rui Zhu  ric Guilbert  Man Sing Wong 《Transactions in GIS》2020,24(1):85-103

Modeling thematic and spatial dynamic behaviors of urban heat islands (UHIs) over time is important for understanding the evolution of this phenomenon to mitigate the warming effect in urban areas. Although previous studies conceptualized that a UHI only has a single life cycle with spatial behaviors, a UHI can be detected to appear and disappear several times periodically in terms of thematic and spatial integrated behaviors. Such multiple behaviors have not yet been illustrated with proof or evidence. This study conceptualizes a UHI as an object which has thematic and spatial behaviors simultaneously and proposes several graphs to depict periodic life‐cycle transitions triggered by behaviors. The conceptualized behaviors have been modeled and implemented in an object‐relational database management system and temperature readings collected from numerous weather stations were interpolated as temperature images per hour. The results of this study indicate that the model could track the spatial and thematic evolution of UHIs continuously and reveal their periodical patterns and abnormal cases.  相似文献   

Comprehensive study of the drying behavior of Boom clay: Experimental investigation and numerical modeling          下载免费PDF全文

Julien Hubert  Erwan Plougonven  Noémie Prime  Angélique Léonard  Frédéric Collin 《国际地质力学数值与分析法杂志》2018,42(2):211-230

This paper presents a thermo‐hydro‐mechanical framework to model the drying behavior of Boom clay. First, the experimental campaign conducted Noémie Prime is briefly presented because it is used to validate the model. The data acquisition and processing is emphasized because of the use of X‐ray microtomography to be able to more accurately compare experimental and numerical strain fields. The different submodels are introduced. Numerical simulations are performed to illustrate the capability of the proposed model to reproduce the observed behavior. Finally, a comprehensive sensitivity study on several key model parameters associated with the water retention curve, and the permeability of the medium, is performed to get a better understanding of the physics behind the coupled model.  相似文献   

Solid–fluid transition modelling in geomaterials and application to a mudflow interacting with an obstacle     

Noémie Prime  Frédéric Dufour  Félix Darve 《国际地质力学数值与分析法杂志》2014,38(13):1341-1361

Given the contrasting behaviour observed for geomaterials, for example, during landslides of the flow type, this contribution proposes an original constitutive model, which associates both an elasto‐plastic relation and a Bingham viscous law linked by a mechanical transition criterion. This last is defined as the second‐order work sign for each material point, which is a general criterion for divergence instabilities. Finite element method with Lagrangian integration points is chosen as a framework for implementing the new model because of its well‐known ability to deal with both solid and fluid behaviours in large deformation processes. A first boundary model considering a sample of initially stable soil, a slope and an obstacle is performed. The results show the power of the constitutive model because the consistent evolution of initiation, propagation and arrest of the mudflow is described. A parametric study is led on various plastic and viscous parameters to determine their influence on the flow development and arrest. Finally, forces against the obstacle are compared with good agreement with those of other authors for the same geometry and a pure viscous behaviour. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Snowpack disrupts relationship between young water fraction and isotope amplitude ratio; approximately one fifth of mountain streamflow less than one year old     

Éowyn M. S. Campbell  Igor Pavlovskii  M. Cathryn Ryan 《水文研究》2020,34(25):4762-4775

Previous “fraction of young water” (F_yw) estimates based on relative annual isotopic amplitudes in precipitation (A_p) and streamflow (A_s) produced low F_yw values in mountain catchments, which is contrary to extensive research that reports rapid water transmission in mountains. This study investigated this discrepancy by testing the effect of snow accumulation on the model that underpins the F_yw method. A Monte-Carlo analysis of simulations for 20,000 randomly-generated catchment model configurations used 10 years of precipitation inputs for the Upper Elbow River catchment in the Rocky Mountains (Alberta, Canada) to model discharge with and without snowpack storage of winter precipitation. Neither direct nor modified precipitation input produced a 1:1 relationship between A_s/A_p and F_yw, undermining the applicability of the original F_yw method in mountain watersheds with large seasonal snow accumulation. With snowpack-modified input a given A_s/A_p ratio corresponds to a range of F_yw values, which can still provide semi-quantitative information. In the small (435 km²) Elbow River catchment a F_yw range of 7–23% supports previous findings of rapid transmission in mountain catchments. Further analysis showed that the improved discharge prediction (Nash–Sutcliffe efficiency > 0.9) correlates with higher F_yw values and demonstrated that the interannual shifts in δ¹⁸O can be used to estimate of new water (<1 year) fraction in winter streamflow, and the estimate of 20% for the Elbow River further supports rapid transmission in mountain catchments.  相似文献   

Post‐orogenic sediment drape in the Northern Pyrenees explained using a box model     

Thomas Bernard  Hugh D. Sinclair  Mark Naylor  Frdric Christophoul  Mary Ford 《Basin Research》2021,33(1):118-137

The transition to a post‐orogenic state in mountain ranges has been identified by a change from active subsidence to isostatic rebound of the foreland basin. However, the nature of the interplay between isostatic rebound and sediment supply, and their impact on the topographic evolution of a range and foreland basin during this transition, has not been fully investigated. Here, we use a box model to explore the syn‐ to post‐orogenic evolution of foreland basin/thrust wedge systems. Using a set of parameter values that approximate the northern Pyrenees and the neighbouring Aquitaine foreland basin, we evaluate the controls on sediment drape over the frontal parts of the retro‐wedge following cessation of crustal thickening. Conglomerates preserved at approximately 600‐m elevation, which is ~ 300 m above the present mountain front in the northern Pyrenees are ca. 12 Ma, approximately 10 Myrs younger than the last evidence of crustal thickening in the wedge. Using the model, this post‐orogenic sediment drape is explained by the combination of a sustained, high sediment influx from the range into the basin relative to the efflux out of the basin, combined with cessation of the generation of accommodation space through basin subsidence. Post‐orogenic sediment drape is considered a generic process that is likely to be responsible for elevated low‐gradient surfaces and preserved remnants of continental sedimentation draping the outer margins of the northern Pyrenean thrust wedge.  相似文献   

SPECTROSCOPOLARIMETRIC SENSING OF ENERGY DEPOSITION INTO THE CHROMOSPHERE DURING SOLAR FLARES – I. Observations     

FIRSTOVA  N. M.  HÉNOUX  J.-C.  KAZANTSEV  S. A.  BULATOV  A. V. 《Solar physics》1997,171(1):123-144

Measurements of linear polarization in hydrogen H and H lines, made with the Large Solar Vacuum Telescope of Baikal Astrophysical Observatory and Automated Solar Telescope of Sayan Solar Observatory, affiliated with the Russian Institute of Solar and Terrestrial Physics, are reported in this paper. Short-term polarization associated with solar flares is found to be present in active regions. There is a significant tendency for the H polarization vector to be radial, i.e., in the flare-to-disk-center direction. This polarization may be due to atmospheric bombardment by hecta keV protons. On the other hand, the polarization vector is found to be perpendicular to the radial direction at some locations where the line profile has a typical mustache shape suggesting a bombardment by energetic electrons. The H line is also linearly polarized. However, no preferential direction of polarization is found in this line, which is formed more deeply in the solar atmosphere.  相似文献   

Performance of CMORPH,TMPA, and PERSIANN rainfall datasets over plain,mountainous, and glacial regions of Pakistan     

Yawar?HussainEmail author  Frédéric?Satgé  Muhammad?Babar?Hussain  Hernan?Martinez-Carvajal  Marie-Paule?Bonnet  Martin?Cárdenas-Soto  Henrique?Llacer?Roig  Gulraiz?Akhter 《Theoretical and Applied Climatology》2018,131(3-4):1119-1132

The present study aims at the assessment of six satellite rainfall estimates (SREs) in Pakistan. For each assessed products, both real-time (RT) and post adjusted (Adj) versions are considered to highlight their potential benefits in the rainfall estimation at annual, monthly, and daily temporal scales. Three geomorphological climatic zones, i.e., plain, mountainous, and glacial are taken under considerations for the determination of relative potentials of these SREs over Pakistan at global and regional scales. All SREs, in general, have well captured the annual north-south rainfall decreasing patterns and rainfall amounts over the typical arid regions of the country. Regarding the zonal approach, the performance of all SREs has remained good over mountainous region comparative to arid regions. This poor performance in accurate rainfall estimation of all the six SREs over arid regions has made their use questionable in these regions. Over glacier region, all SREs have highly overestimated the rainfall. One possible cause of this overestimation may be due to the low surface temperature and radiation absorption over snow and ice cover, resulting in their misidentification with rainy clouds as daily false alarm ratio has increased from mountainous to glacial regions. Among RT products, CMORPH-RT is the most biased product. The Bias was almost removed on CMORPH-Adj thanks to the gauge adjustment. On a general way, all Adj versions outperformed their respective RT versions at all considered temporal scales and have confirmed the positive effects of gauge adjustment. CMORPH-Adj and TMPA-Adj have shown the best agreement with in situ data in terms of Bias, RMSE, and CC over the entire study area.  相似文献   

Defining deep decarbonization pathways for Switzerland: an economic evaluation     

Frédéric Babonneau  Philippe Thalmann 《Climate Policy》2018,18(1):1-13

This article simulates deep decarbonization pathways for a small open economy that lacks the usual avenues for large CO₂ reductions – heavy industry and power generation. A computable general equilibrium model is used to assess the energy and economic impacts of the transition to only one ton of CO₂ emissions per capita in 2050. This represents a 76% reduction with respect to 1990 levels, while the population is expected to be 46% larger and GPD to increase by 90%. The article discusses several options and scenarios that are compatible with this emissions target and compares them with a reference scenario that extrapolates already-decided climate and energy policy instruments. We show that the ambitious target is attainable at moderate welfare costs, even if it needs very high carbon prices, and that these costs are lower when either CO₂ can be captured and sequestered or electricity consumption can be taxed sufficiently to stabilize it.

Policy relevance

In the context of COP 21, all countries must propose intended contributions that involve deep decarbonization of their economy over the next decades. This article defines and analyses such pathways for Switzerland, taking into consideration the existing energy demand and supply and also already-defined climate policies. It draws several scenarios that are compatible with a target of 1 ton of CO₂ emissions per capita in 2050. This objective is very challenging, especially with the nuclear phase out decided after the disaster in Fukushima and the political decision to balance electricity trade. Nevertheless, it is possible to design several feasible pathways that are based on different options. The economic cost is significant but affordable for the Swiss economy. The insights are relevant not only for Switzerland, but also for other industrialized countries when defining their INDCs.  相似文献   

Enhanced Oxygen Isotope Determination in Uranium Oxides Using BrF5 Fluorination          下载免费PDF全文

Malorie Dierick  Éric Pili  Nelly Assayag  Pierre Agrinier 《Geostandards and Geoanalytical Research》2017,41(3):397-409

A new method for accurate determination of oxygen isotopes in uranium oxides encountered in the nuclear fuel cycle was developed using the conventional BrF₅ fluorination technique. Laser‐assisted fluorination was tested for comparison. We focused on fine powders of triuranium octoxide (U₃O₈), uranium dioxide (UO_2±x with 0 ≤ x ≤ 0.25), uranium trioxide (UO₃.nH₂O, with 0.8 ≤ n ≤ 2) and diuranates (M₂U₂O₇.nH₂O, with M = NH₄, Na or Mg_0.5 and 0 ≤ n ≤ 6). Fluorination at room temperature and heating under vacuum at 150 °C are shown to eliminate both adsorbed and structural water from the powder samples. Precision fit for purpose of δ¹⁸O values (± 0.3‰, 1s) and oxygen yields (close to 100%) were obtained for U₃O₈ and UO₂ where oxygen is only bound to uranium. A lower precision was observed for UO₃.nH₂O and M₂U₂O₇.nH₂O where oxygen is both present in the structural H₂O and bonded to uranium and where the extracted O_2(g) can be contaminated by NF₃ and NO_x compounds. Laser‐assisted fluorination gave shifted δ¹⁸O values between +0.8 and +1.4‰ for U₃O₈, around ?0.8‰ for UO₃.nH₂O and between ?3.9 and ?4.5‰ for M₂U₂O₇.nH₂O (± 0.3‰, 1s) compared with the conventional method.  相似文献